Carbon dioxide fixation - Copper(II) and zinc(II) complexes can fix atmospheric carbon dioxide

被引：131

作者：

Kong, LY

Zhang, ZH

Zhu, HF

Kawaguchi, H

Okamura, T

Doi, M

Chu, Q

Sun, WY ^{[1
]}

Ueyama, N

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448585, Japan

[3] Osaka Univ, Dept Macromol Sci, Toyonaka, Osaka 560, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期

关键词：

carbon dioxide fixation; copper; networks; NMR spectroscopy; zinc;

D O I：

10.1002/anie.200500587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Carbonato bridges from atmospheric carbon dioxide: The copper(II) and zinc(II) complexes of the novel imidazole-containing polyamine ligand N1-(2-aminoethyl)-N1-(2-imidazolethyl) ethane-1,2-diamine are found to fix carbon dioxide by hydration to μ3-carbonate ligands. This is revealed by IR and solid-state 13C NMR spectroscopic and X-ray crystallographic studies of the two-dimensional complexes (see picture). © 2005 Wiley-VCH Verlag GmbH £ Co. KGaA.

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收藏

页码：4352 / 4355

页数：4

相关论文

共 29 条

[11] Spontaneous carbon dioxide fixation:: a μ4-carbonate bridged tetranuclear zinc(II) complex of a heptadentate Schiff base [J].

Fondo, M ;

García-Deibe, AM ;

Bermejo, MR ;

Sanmartín, J ;

Llamas-Saiz, AL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (24) :4746-4750

[12] CO2 fixation by copper(II) complexes of a terpyridinophane aza receptor [J].

García-España, E ;

Gaviña, P ;

Latorre, J ;

Soriano, C ;

Verdejo, BA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5082-5083

[13] FACILE CO2 UPTAKE BY ZINC(II) TETRAAZACYCLOALKANE COMPLEXES .1. SYNTHESES, CHARACTERIZATIONS, AND CHEMICAL-PROPERTIES OF (MONOALKYL CARBONATO)(TETRAAZACYCLOALKANE)ZINC(II) COMPLEXES [J].

KATO, M ;

ITO, T .

INORGANIC CHEMISTRY, 1985, 24 (04) :504-508

[14] Isolation and characterization of the first stable bicarbonato complex in a nickel(II) system: identification of unusual monodentate coordination [J].

Kim, JC ;

Cho, JH ;

Kim, H ;

Lough, AJ .

CHEMICAL COMMUNICATIONS, 2004, (16) :1796-+

[15] Model studies for molecular recognition of carbonic anhydrase and carboxypeptidase [J].

Kimura, E .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (02) :171-179

[16] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[17] The coordination chemistry of carbon dioxide and its relevance for catalysis: A critical survey [J].

Leitner, W .

COORDINATION CHEMISTRY REVIEWS, 1996, 153 :257-284

[18] Isolation and characterization of the first stable bicarbonato complexes of bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-like intermediates [J].

Mao, ZW ;

Liehr, G ;

van Eldik, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (19) :4839-4840

[19] Reaction of (μ-oxo)diiron(III) core with CO2 in N-methylimidazole:: Formation of mono(μ-carboxylato)(μ-oxo)diiron(III) complexes with N-methylimidazole as ligands [J].

Marlin, DS ;

Olmstead, MM ;

Mascharak, PK .

INORGANIC CHEMISTRY, 2003, 42 (05) :1681-1687

[20] An intramolecular H3O2 bridge as the resting form of an active metal-bound hydroxide in a dinuclear zinc(II) complex [J].

Meyer, F ;

Rutsch, P .

CHEMICAL COMMUNICATIONS, 1998, (09) :1037-1038