CO2 fixation by copper(II) complexes of a terpyridinophane aza receptor

被引:82
作者
García-España, E
Gaviña, P
Latorre, J
Soriano, C
Verdejo, BA
机构
[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan & Organ, E-46100 Burjassot, Valencia, Spain
[2] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Valencia, Spain
关键词
D O I
10.1021/ja039577h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CO2 is fixed by a Cu2+ complex of a macrocyclic terpyridinophane ligand forming a carbamate group. Several features of the structure mimic the enzyme rubisco. Copyright © 2003 American Chemical Society.
引用
收藏
页码:5082 / 5083
页数:2
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