An intramolecular H3O2 bridge as the resting form of an active metal-bound hydroxide in a dinuclear zinc(II) complex

被引:113
作者
Meyer, F [1 ]
Rutsch, P [1 ]
机构
[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1039/a800412i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An intramolecular Zn-O2H3-Zn bridge as a complexed form of metal-bound hydroxide exhibits enhanced reactivity compared to the related Zn-OH-Zn unit, illustrated by the reaction with CO2.
引用
收藏
页码:1037 / 1038
页数:2
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