Non-ionic Thermoresponsive Polymers in Water

被引：501

作者：

Aseyev, Vladimir ^{[1
]}

Tenhu, Heikki ^{[1
]}

Winnik, Francoise M. ^{[2
,3
]}

机构：

[1] Univ Helsinki, Dept Chem, Polymer Chem Lab, FIN-00014 Helsinki, Finland

[2] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

[3] Univ Montreal, Fac Pharm, Montreal, PQ H3C 3J7, Canada

来源：

SELF ORGANIZED NANOSTRUCTURES OF AMPHIPHILIC BLOCK COPOLYMERS II | 2011年 / 242卷

关键词：

Amphiphilic; LCST; Polymer; Solution; Thermoresponsive; Water; CRITICAL SOLUTION TEMPERATURE; COIL-GLOBULE TRANSITION; FRAGMENTATION CHAIN TRANSFER; LIVING CATIONIC-POLYMERIZATION; AMPHIPHILIC BLOCK-COPOLYMERS; TRANSFER RADICAL POLYMERIZATION; AQUEOUS SALT-SOLUTIONS; DIFFERENTIAL SCANNING CALORIMETRY; INDUCED PHASE-TRANSITION; CLOUD POINT CURVES;

D O I：

10.1007/12_2010_57

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

Numerous non-ionic thermally responsive homopolymers phase separate from their aqueous solutions upon heating. Far fewer neutral homopolymers are known to phase separate upon cooling. A systematic compilation of the polymers reported to exhibit thermoresponsive behaviour is presented in this review, including N-substituted poly[(meth)acrylamide]s, poly(N-vinylamide)s, poly(oxazoline)s, protein-related polymers, poly(ether)s, polymers based on amphiphilic balance, and elastin-like synthetic polymers. Basic properties of aqueous solutions of these polymers are briefly described.

引用

页码：29 / 89

页数：61

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