New examples of metalloaromatic Al-clusters:: (Al4M4)Fe(CO)3 (M = Li, Na and K) and (Al4M4)2Ni:: rationalization for possible synthesis

被引：23

作者：

Datta, A

Pati, SK

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, Theoret Sci Unit, Bangalore, Karnataka, India

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 40期

关键词：

D O I：

10.1039/b508123h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ab initio calculations reveal that all-metal antiaromatic molecules like Al4M4 (M = Li, Na and K) can be stabilized in half sandwich (Al4M4)Fe(CO)(3) and full sandwich (Al4M4)(2)Ni complexes. The formation of the full sandwich complex [(Al4M4)(2)Ni] from its organometallic precursor depends on the stability of the organic-inorganic hybrid (C4H4)Ni(Al4Li4).

引用

页码：5032 / 5034

页数：3

共 27 条

[1] Do all-metal antiaromatic clusters exist? [J].