A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups

被引：156

作者：

Custelcean, R ^{[1
]}

Moyer, BA

Hay, BP

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Pacific NW Natl Lab, Div Chem Sci, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 48期

关键词：

D O I：

10.1039/b511809c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a 1D metal - organic framework that encapsulates SO42- anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.

引用

页码：5971 / 5973

页数：3

共 52 条

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