The charge-reverse analogy as an inspiration for the preparation of polydentate Lewis acidic boranes

被引：60

作者：

Gabbaï, FP ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 20期

关键词：

adduct formation; anions; boraarenes; Lewis acids; organoboron chemistry;

D O I：

10.1002/anie.200301630

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reversing the charge: The recent preparation of a masked version of a 2,2′-diborabiphenyl (the radical anion of its adduct with benzo[c]cinnoline is shown) constitutes a noticeable achievement on the way to bidentate Lewis acidic boranes with optimized properties as ligands and opens up the chemistry of this unique class of bidentate Lewis acids.

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页码：2218 / 2221

页数：4

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