Selective domino ring-closing metathesis-cross-metathesis reactions between enynes and electron-deficient alkenes

被引：65

作者：

Royer, F ^{[1
]}

Vilain, C ^{[1
]}

Elkaïm, L ^{[1
]}

Grimaud, L ^{[1
]}

机构：

[1] Ecole Natl Super Tech Avancees, Lab Chim & Proc, F-75739 Paris 15, France

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 11期

关键词：

D O I：

10.1021/ol034620r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHIC] A selective domino ring-closing metathesis (RCM)-cross-metathesis (CM) process between enynes and electron-deficient alkenes is reported. The conditions have been optimized for enynes 3 and methyl acrylate with catalyst IV. The scope and limitations of this reaction are described, and a possible mechanism is discussed.

引用

页码：2007 / 2009

页数：3

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