Disproportionation and transalkylation of alkylbenzenes over zeolite catalysts

被引:363
作者
Tsai, TC
Liu, SB
Wang, IK [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 300, Taiwan
[2] Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan
[3] Chinese Petrol Corp, Refining & Mfg Res Ctr, Chiayi 600, Taiwan
基金
欧盟地平线“2020”;
关键词
disproportionation; transalkylation; alkylbenzenes; zeolites; diffusivity;
D O I
10.1016/S0926-860X(98)00396-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Disproportionation and transalkylation are important processes for the interconversion of mono-, di-, and tri-alkylbenzenes. In this review, we discuss the recent advances in process technology with special focus on improvements of para-isomer selectivity and catalyst stability. Extensive patent search and discussion on technology development are presented. The key criteria for process development are identified. The working principles of para-isomer selectivity improvements involve the reduction of diffusivity and the inactivation of external surface. In conjunction with the fundamental research, various practical modification aspects particularly the pre-coking and the silica deposition techniques, are extensively reviewed. The impact of para-isomer selective technology on process economics and product recovery strategy is discussed. Furthermore, perspective trends in related research and development are provided. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:355 / 398
页数:44
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