Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

被引：51

作者：

Xu, Y ^{[1
]}

Zhu, DR ^{[1
]}

Guo, ZJ ^{[1
]}

Shi, YJ ^{[1
]}

Zhang, KL ^{[1
]}

You, XZ ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 06期

关键词：

clusters; structural studies; template synthesis; molybdenum; vanadium;

D O I：

10.1039/b010227j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel hexadecametal-oxygen cluster compounds, {Ni[(NH2)(2)(C2H4)(2)NH](2)}(3)[(PMo5Mo3V8O44)-Mo-VI-V-V-O-IV].[(NH2)(2)(C2H4)(2)NH].H2O 1 and {Co[(NH2)(2)(C2H4)(2)NH](2)}(2)Na[(PMo6Mo2V8O44)-Mo-VI-V-V-O-IV]. 8H(2)O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal-oxygen host shell is observed in 2.

引用

页码：772 / 773

页数：2

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