Stereoselective electrochemical transformation of alkylidenecyanoacetates and malonate into (E)-3-substituted-2-cyanocyclopropane-1,1,2-tricarboxylates

被引：39

作者：

Elinson, MN

Feducovich, SK

Starikova, ZA

Olessova, OS

Vereshchagin, AN

Nikishin, GI

机构：

[1] ND Zelinskii Inst Organ Chem, Moscow 117913, Russia

[2] AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 25期

基金：

俄罗斯基础研究基金会;

关键词：

electrochemical reactions; stereoselectivity; catalysis; cyclopropanes;

D O I：

10.1016/S0040-4039(00)00733-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Electrolysis of malonate and alkylidenecyanoacetates in alcohols in the presence of sodium bromide in an undivided cell results in the stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75-85% yields. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4937 / 4941

页数：5

共 12 条

[1]

BONAVENT G, 1964, B SOC CHIM FR, P2462

[2]

REACTIONS OF CARBANIONS WITH ELECTRON-ACCEPTORS [J].