One-pot synthesis of well-defined amphiphilic and adaptative block copolymers via versatile combination of "Click" chemistry and ATRP

被引：73

作者：

Mespouille, Laetitia

Vachaudez, Magali

Suriano, Fabian

Gerbaux, Pascal

Coulembier, Olivier

Degee, Philippe

Flammang, Robert

Dubois, Philippe

机构：

[1] Univ Mons, Ctr Innovat & Res Mat, Lab Polymer & Composite Mat, B-7000 Mons, Belgium

[2] Univ Mons, Organ Chem Lab, B-7000 Mons, Belgium

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 22期

关键词：

D O I：

10.1002/marc.200700400

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-defined amphiphilic PCL-b-PDMAEMA block copolymers were successfully synthesized by a combination of ATRP and "click" chemistry following either a commutative two-step procedure or a straightforward one-pot process using CuBr center dot 3Bpy as the sole catalyst. Compared to the traditional coupling method, combining ATRP and click chemistry even in a "one-pot" process allows the preparation of PCL-b-PDMAEMA diblock copolymers characterized by

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页码：2151 / 2158

页数：8

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