Correlation between thermal fluctuation effects and phase coherence factor in carrier transport of single-crystal organic semiconductors

被引:15
作者
Fukami, Tatsuya [1 ,2 ]
Ishii, Hiroyuki [1 ,2 ,3 ]
Kobayashi, Nobuhiko [1 ,2 ]
Uemura, Takafumi [4 ]
Sakai, Kenichi [4 ]
Okada, Yugo [4 ]
Takeya, Jun [4 ]
Hirose, Kenji [5 ]
机构
[1] Univ Tsukuba, Inst Appl Phys, Tsukuba, Ibaraki 3058573, Japan
[2] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci, Tsukuba, Ibaraki 3058573, Japan
[3] JST Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
[4] Univ Tokyo, Dept Adv Mat Sci, Kashiwa, Chiba 2778561, Japan
[5] NEC Corp Ltd, Green Innovat Res Labs, Tsukuba, Ibaraki 3058501, Japan
关键词
D O I
10.1063/1.4916734
中图分类号
O59 [应用物理学];
学科分类号
摘要
We find that the phase coherence factor derived from Hall effect measurements of single-crystal thin-film field-effect transistors of pentacene, which relates the intrinsic charge transport with the phase coherence, has a strong correlation with the thermal fluctuations of transfer energies between neighboring molecules. This observation also holds true for other organic semiconductors such as tetracene, dianthrathiophene (DAT)-V, and dinaphtho[2,3-b:2',3'-f] thieno[3,2-b] thiophene ( DNTT). This gives us clues for constructing flexible molecular systems with high carrier mobility. (C) 2015 AIP Publishing LLC.
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页数:4
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共 20 条
[11]   Quantum coherence and carriers mobility in organic semiconductors [J].
Picon, J.-D. ;
Bussac, M. N. ;
Zuppiroli, L. .
PHYSICAL REVIEW B, 2007, 75 (23)
[12]   GENERAL ATOMIC AND MOLECULAR ELECTRONIC-STRUCTURE SYSTEM [J].
SCHMIDT, MW ;
BALDRIDGE, KK ;
BOATZ, JA ;
ELBERT, ST ;
GORDON, MS ;
JENSEN, JH ;
KOSEKI, S ;
MATSUNAGA, N ;
NGUYEN, KA ;
SU, SJ ;
WINDUS, TL ;
DUPUIS, M ;
MONTGOMERY, JA .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 1993, 14 (11) :1347-1363
[13]   ON RIGID-BODY MOTION OF MOLECULES IN CRYSTALS [J].
SCHOMAKER, V ;
TRUEBLOOD, KN .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :63-+
[14]   In-crystal and surface charge transport of electric-field-induced carriers in organic single-crystal semiconductors [J].
Takeya, J. ;
Kato, J. ;
Hara, K. ;
Yamagishi, M. ;
Hirahara, R. ;
Yamada, K. ;
Nakazawa, Y. ;
Ikehata, S. ;
Tsukagoshi, K. ;
Aoyagi, Y. ;
Takenobu, T. ;
Iwasa, Y. .
PHYSICAL REVIEW LETTERS, 2007, 98 (19)
[15]   Roles of intramolecular and intermolecular electron-phonon coupling on the formation and transport of large polarons in organic semiconductors [J].
Tamura, Hiroyuki ;
Tsukada, Masaru ;
Ishii, Hiroyuki ;
Kobayashi, Nobuhiko ;
Hirose, Kenji .
PHYSICAL REVIEW B, 2012, 86 (03)
[16]   Charge-transport regime of crystalline organic semiconductors: Diffusion limited by thermal off-diagonal electronic disorder [J].
Troisi, A ;
Orlandi, G .
PHYSICAL REVIEW LETTERS, 2006, 96 (08)
[17]   Dynamics of the intermolecular transfer integral in crystalline organic semiconductors [J].
Troisi, A ;
Orlandi, G .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (11) :4065-4070
[18]   Temperature dependence of the Hall effect in pentacene field-effect transistors: Possibility of charge decoherence induced by molecular fluctuations [J].
Uemura, T. ;
Yamagishi, M. ;
Soeda, J. ;
Takatsuki, Y. ;
Okada, Y. ;
Nakazawa, Y. ;
Takeya, J. .
PHYSICAL REVIEW B, 2012, 85 (03)
[19]   Effect of electronic polarization on charge-transport parameters in molecular organic semiconductors [J].
Valeev, Edward F. ;
Coropceanu, Veaceslav ;
da Silva Filho, Demetrio A. ;
Salman, Seyhan ;
Bredas, Jean-Luc .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9882-9886
[20]   Free-electron-like Hall effect in high-mobility organic thin-film transistors [J].
Yamagishi, M. ;
Soeda, J. ;
Uemura, T. ;
Okada, Y. ;
Takatsuki, Y. ;
Nishikawa, T. ;
Nakazawa, Y. ;
Doi, I. ;
Takimiya, K. ;
Takeya, J. .
PHYSICAL REVIEW B, 2010, 81 (16)