Electrical conductance of polyelectrolyte gels

被引：49

作者：

Gong, JP ^{[1
]}

Komatsu, N ^{[1
]}

Nitta, T ^{[1
]}

Osada, Y ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV BIOL SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 05期

关键词：

D O I：

10.1021/jp963059u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An attempt to establish a systematic method to precisely evaluate the electrical conductivity of highly water-swollen polyelectrolyte gels was made. It was found that the electrical conductivity and the activation energy of fully ionized polyelectrolyte gel such as cross-linked poly(3-acrylamido-2-methylpropanesulfonic acid) gels with various counterions are almost identical with those of linear polymer in a wide range of swelling, indicating that the conduction of an ionic gel is essentially performed by the ''free'' counterions of Manning's condensation theory.

引用

页码：740 / 745

页数：6

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[No title captured]

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