The role of Cr in promoting protective alumina scale formation by gamma-based Ti-Al-Cr alloys .2. Oxidation behavior in air

被引:111
作者
Brady, MP [1 ]
Smialek, JL [1 ]
Humphrey, DL [1 ]
Smith, J [1 ]
机构
[1] NASA, LEWIS RES CTR, CLEVELAND, OH 44135 USA
基金
美国国家航空航天局;
关键词
D O I
10.1016/S1359-6454(96)00361-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The oxidation behavior of single-phase gamma, single-phase Laves, and two-phase gamma + Laves Ti-Al-Cr alloys was investigated at 1000 degrees C in air. The addition of 4-5 at.% Cr to the gamma phase resulted in protective alumina scale formation in dry air, but titania-based nodule formation in humid room air. Two-phase gamma + Laves alloys exhibited protective alumina scale formation in both dry air and humid room air. The difference in oxidation behavior between gamma and gamma + Laves alloys was interpreted in terms of compositional changes at the alloy/scale interface during oxidation. (C) 1997 Acta Metallurgica Inc.
引用
收藏
页码:2371 / 2382
页数:12
相关论文
共 19 条
[1]   MECHANISM OF ISOTHERMAL OXIDATION OF THE INTERMETALLIC TIAL AND OF TIAL ALLOYS [J].
BECKER, S ;
RAHMEL, A ;
SCHORR, M ;
SCHUTZE, M .
OXIDATION OF METALS, 1992, 38 (5-6) :425-464
[2]  
Berztiss D. A., 1995, High-Temperature Ordered Intermetallic Alloys VI. Symposium, P1285
[3]  
Brady M. P., 1995, High-Temperature Ordered Intermetallic Alloys VI. Symposium, P1309
[4]   The oxidation and protection of gamma titanium aluminides [J].
Brady, MP ;
Brindley, WJ ;
Smialek, JL ;
Locci, IE .
JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 1996, 48 (11) :46-50
[5]   Modification of microstructure for improved oxidation resistance in gamma-based Ti-Al-X alloys [J].
Brady, MP ;
Smialek, JL ;
Verink, ED ;
Hoelzer, DT ;
Stone, R .
MATERIALS AND MANUFACTURING PROCESSES, 1996, 11 (04) :635-653
[6]   MICROSTRUCTURE OF ALUMINA-FORMING OXIDATION-RESISTANT AL-TI-CR ALLOYS [J].
BRADY, MP ;
SMIALEK, JL ;
TEREPKA, F .
SCRIPTA METALLURGICA ET MATERIALIA, 1995, 32 (10) :1659-1664
[7]  
CHOUDHURY NS, 1976, PROPERTIES HIGH TEMP, P668
[8]   EFFECT OF HYDROGEN AS A TEMPORARY BETA-STABILIZER ON MICROSTRUCTURE AND BRITTLE-FRACTURE BEHAVIOR IN A TITANIUM ALUMINIDE ALLOY [J].
CHU, WY ;
THOMPSON, AW .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1991, 22 (01) :71-81
[9]  
Dettenwanger F., 1995, High-Temperature Ordered Intermetallic Alloys VI. Symposium, P981
[10]  
Hayes F.H., 1992, J PHASE EQUILIB, V13, P79, DOI DOI 10.1007/BF02645384