Spontaneous oxidation of C60Ph5X (X=H, Cl) to a benzo[b]furanyl[60]fullerene

被引：32

作者：

Avent, AG ^{[1
]}

Birkett, PR ^{[1
]}

Darwish, AD ^{[1
]}

Kroto, HW ^{[1
]}

Taylor, R ^{[1
]}

Walton, DRM ^{[1
]}

机构：

[1] UNIV SUSSEX,CPES SCH,CHEM LAB,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703803h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On exposure to air, both C60Ph5H and C60Ph5Cl spontaneously oxidise with elimination of the hydrogen or chlorine attached to the cage and the ortho hydrogen of the adjacent phenyl group, giving a benzo[b]furanyl[60] fullerene; a second oxygen is located in the pentagon that is surrounded by phenyl groups.

引用

页码：1579 / 1580

页数：2

共 39 条

[1] PHOTOCHEMICAL [2+3] CYCLOADDITION OF C-60 WITH DISILIRANES [J].

AKASAKA, T ;

ANDO, W ;

KOBAYASHI, K ;

NAGASE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :10366-10367

[2] THE STRUCTURE OF C60PH5CL AND C60PH5H, FORMED VIA ELECTROPHILIC AROMATIC-SUBSTITUTION [J].

AVENT, AG ;

BIRKETT, PR ;

CRANE, JD ;

DARWISH, AD ;

LANGLEY, GJ ;

KROTO, HW ;

TAYLOR, R ;

WALTON, DRM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1463-1464

[3] CYCLOADDITIONS .48. ADDITION OF PHOTOCHEMICALLY GENERATED ACYLNITRENES TO C-60 - SYNTHESIS OF FULLEROAZIRIDINES AND THERMAL REARRANGEMENT TO FULLEROOXAZOLES [J].

AVERDUNG, J ;

MATTAY, J ;

JACOBI, D ;

ABRAHAM, W .

TETRAHEDRON, 1995, 51 (09) :2543-2552

[4] Progress in fullerene chemistry: From exohedral functionalization to heterofullerenes [J].

Averdung, J ;

TorresGarcia, G ;

Luftmann, H ;

Schlachter, I ;

Mattay, J .

FULLERENE SCIENCE AND TECHNOLOGY, 1996, 4 (04) :633-654

[5]

AVERDUNG J, 1996, TETRAHEDRON LETT, P4683

[6] OXIDATION OF BUCKMINSTERFULLERENE WITH M-CHLOROPEROXYBENZOIC ACID - CHARACTERIZATION OF A C-S ISOMER OF THE DIEPOXIDE C60O2 [J].

BALCH, AL ;

COSTA, DA ;

NOLL, BC ;

OLMSTEAD, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (35) :8926-8932

[7] BIS-FUNCTIONALIZATION OF C-60 VIA THERMAL REARRANGEMENT OF AN ISOLABLE FULLEROAZIRIDINE BEARING A SOLUBILIZING SUPERMESITYL ESTER MOIETY [J].

BANKS, MR ;

CADOGAN, JIG ;

GOSNEY, I ;

HODGSON, PKG ;

LANGRIDGESMITH, PRR ;

RANKIN, DWH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1365-1366

[8] Isolation and characterisation of C70O [J].

Bezmelnitsin, VN ;

Eletskii, AV ;

Schepetov, NG ;

Avent, AG ;

Taylor, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (04) :683-686

[9]

BIRKETT PR, UNPUB

[10]

BRIZZOLARA D, 1993, B SOC CHIM FR, V130, P745

← 1 2 3 4 →