Nonequilibrium thermodynamics in engineering and science

被引:86
作者
Demirel, YA [1 ]
Sandler, SI
机构
[1] Virginia Polytech Inst & State Univ, Dept Chem Engn, Blacksburg, VA 24061 USA
[2] Univ Delaware, Dept Chem Engn, Ctr Mol & Engn Thermodynam, Newark, DE 19716 USA
关键词
D O I
10.1021/jp030405g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The field of nonequilibrium thermodynamics has been a popular one outside the United States, especially in Europe, and scientists there from various disciplines have published extensively on the use of nonequilibrium thermodynamics in a large variety of biological, chemical, and mechanical engineering applications. In contrast, the number of publications from North America has been relatively modest. Here, we review the field of nonequilibrium thermodynamics to assess its utility and impact in engineering and science. We find that developments in the fields thermodynamic optimality of processes, dissipative structures, coupled transport and rate processes, and biological systems suggest that in some circumstances nonequilibrium thermodynamics can be quite useful.
引用
收藏
页码:31 / 43
页数:13
相关论文
共 102 条
[51]   A simple example for comparing GENERIC with rational non-equilibrium thermodynamics [J].
Muschik, W ;
Gümbel, S ;
Kröger, M ;
Öttinger, HC .
PHYSICA A, 2000, 285 (3-4) :448-466
[53]   A thermodynamic principle for the coupled bioenergetic processes of ATP synthesis [J].
Nath, S .
PURE AND APPLIED CHEMISTRY, 1998, 70 (03) :639-644
[54]  
NETTLETON RE, 1995, J NON-EQUIL THERMODY, V20, P205, DOI 10.1515/jnet.1995.20.3.205
[55]  
NICOLI S, 1977, SELF ORG NONEQUILIBR
[56]   Metabolic control analysis of biochemical pathways based on a thermokinetic description of reaction rates [J].
Nielsen, J .
BIOCHEMICAL JOURNAL, 1997, 321 :133-138
[57]   Reciprocal relations in irreversible processes. I. [J].
Onsager, L .
PHYSICAL REVIEW, 1931, 37 (04) :405-426
[58]   Reciprocal relations in irreversible processes. II. [J].
Onsager, L .
PHYSICAL REVIEW, 1931, 38 (12) :2265-2279
[59]   Catalysis and non-equilibrium thermodynamics: modern in situ studies and new theoretical approaches [J].
Parmon, VN .
CATALYSIS TODAY, 1999, 51 (3-4) :435-456
[60]  
Paterson R., 1988, SWISS CHEM, V10, P17