Pd catalyzed kinetic resolution of conduritol B. Asymmetric synthesis of (+)-cyclophellitol

被引：54

作者：

Trost, BM ^{[1
]}

Hembre, EJ ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(98)02274-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomerically pure (+)-cyclophellitol is readily available from benzoquinone employing an asymmetric palladium catalyzed kinetic resolution of racemic conduritol B and a novel easily cleavable pivalate analogue. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：219 / 222

页数：4

共 23 条

[21] A MODULAR APPROACH FOR LIGAND DESIGN FOR ASYMMETRIC ALLYLIC ALKYLATIONS VIA ENANTIOSELECTIVE PALLADIUM-CATALYZED IONIZATIONS [J].