Copper-Catalyzed Formic Acid Synthesis from CO2 with Hydrosilanes and H2O

被引：152

作者：

Motokura, Ken ^{[1
]}

Kashiwame, Daiki ^{[1
]}

Miyaji, Akimitsu ^{[1
]}

Baba, Toshihide ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Environm Chem & Engn, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 10期

关键词：

CARBON-DIOXIDE; HYDROLYTIC OXIDATION; HYDROGENATION; REDUCTION; COMPLEXES; HYDROSILYLATION; SILANOLS; ORGANOSILANES; CONVERSION; METHANOL;

D O I：

10.1021/ol301034j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper-catalyzed formic acid synthesis from CO2 with hydrosilanes has been accomplished. The Cu(OAc)(2)center dot H2O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO2. The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.

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收藏

页码：2642 / 2645

页数：4

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