Contamination of magadiite by fluorine in commonly used synthetic procedures

被引:2
作者
Binette, MJ [1 ]
Detellier, C [1 ]
机构
[1] Univ Ottawa, Ottawa Carleton Chem Inst, Dept Chem, Ottawa, ON K1N 6N5, Canada
关键词
fluorine; lamellar polysilicates; magadiite; synthetic procedures;
D O I
10.1346/CCMN.1998.0460412
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the paper, the results of studying fluorine contamination of magadiite (a layered silicate) during the synthesis in a Teflon-lined autoclave at high temperatures are presented. The crystal structure of the synthetic mineral was confirmed by X ray powder diffraction data. The fluorine impurities were determined using 19F magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy and ionic chromatography technique.
引用
收藏
页码:478 / 480
页数:3
相关论文
共 14 条
[11]  
ROONEY TP, 1969, AM MINERAL, V54, P1034
[12]   PILLARING OF MAGADIITE WITH SILICATE SPECIES [J].
SPRUNG, R ;
DAVIS, ME ;
KAUFFMAN, JS ;
DYBOWSKI, C .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (02) :213-220
[13]   Hybrid organic-inorganic nanocomposites formed from an epoxy polymer and a layered silicic acid (magadiite) [J].
Wang, Z ;
Lan, T ;
Pinnavaia, TJ .
CHEMISTRY OF MATERIALS, 1996, 8 (09) :2200-&
[14]   PREPARATION AND CHARACTERIZATION OF PILLARED MAGADIITE [J].
WONG, ST ;
CHENG, SF .
CHEMISTRY OF MATERIALS, 1993, 5 (06) :770-777