Synthesis and structural study of a tetranuclear magnesium alkoxide: [Mg-4(mu(3),eta(2)-OR)(2)(mu(2),eta(2)-OR)(4)(OR)(2)] with OR=OCH(CH3)CH2OCH3

被引：18

作者：

Albaric, L

Hovnanian, N

Julbe, A

Guizard, C

AlvarezLarena, A

Piniella, JF

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,MAT & PROCEDES MEMBRANAIRES,CNRS,URA 9987,F-34053 MONTPELLIER 1,FRANCE

[2] UNIV AUTONOMA BARCELONA,DEPT GEOL,UNIDAD CRISTALOG & MINERAL,BELLATERRA 08193,SPAIN

来源：

POLYHEDRON | 1997年 / 16卷 / 04期

关键词：

magnesium; alkoxide; X-ray crystallography; sol-gel; molecular precursor of oxide material;

D O I：

10.1016/0277-5387(96)00327-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct reaction between magnesium and 1-methoxy-2-propanol yielded the title complex which has been characterized by X-ray crystallography. The molecular structure consists of a centrosymmetric tetrameric unit in which the Mg atoms are five- or six-coordinated by terminal, triple- and double-bridging chelating alkoxo ligands. Copyright (C) 1996 Elsevier Science Ltd

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页码：587 / 592

页数：6

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