Multiple internal reflection FTIR spectroscopic (MIRFTIRS) study of the redox process of poly(5-amino-1,4-naphthoquinone) film in aqueous and organic media

被引：24

作者：

Piro, B

Bazzaoui, EA

Pham, MC

Novak, P

Haas, O

机构：

[1] Univ Paris 07, Inst Topol & Dynam Syst, CNRS, URA 34, F-75005 Paris, France

[2] Paul Scherrer Inst, Electrochem Sect, CH-5232 Villigen, Switzerland

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 12期

关键词：

multiple internal reflection; aqueous media; organic media; poly(5-amino-1,4-naphthoquinone);

D O I：

10.1016/S0013-4686(98)00304-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Poly(S-amino-1,4-naphthoquinone), PANQ, films are electroactive in both aqueous and organic solutions. The redox process of both the film and the quinone groups has been studied by MIRFTIRS and Probe Beam Deflection. The quinone system is very stable in acetonitrile and in aqueous solutions up to pH 11, Therefore, its redox properties suggest potential applications in diverse areas. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1953 / 1964

页数：12

共 18 条

[1]

AUDEBERT P, 1986, J CHEM SOC CHEM COMM, V887

[2] PROBE BEAM DEFLECTION - A USEFUL TOOL FOR THE STUDY OF ION-TRANSPORT IN POLYMERS [J].