Gold catalyzed oxycyclizations of alkynols and alkyndiols

被引：111

作者：

Alcaide, Benito ^{[1
]}

Almendros, Pedro ^{[2
]}

Miguel Alonso, Jose ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ 1, Unidad Asociada CSIC,Grp Lactamas & Heterociclos, E-28040 Madrid, Spain

[2] CSIC, Inst Quim Organ Gen, Consejo Super Invest Cient, IQOG, E-28006 Madrid, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 12期

关键词：

VERSATILE BUILDING-BLOCKS; HIGHLY EFFICIENT ACCESS; MARINE NATURAL-PRODUCTS; INTRAMOLECULAR CYCLIZATION; ENANTIOSELECTIVE SYNTHESIS; POLYSUBSTITUTED FURANS; C-C; STRUCTURAL ELUCIDATION; EXPEDITIOUS SYNTHESIS; ACETYLENIC ALCOHOLS;

D O I：

10.1039/c1ob05249g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynols and alkyndiols represent excellent building blocks for oxycyclization reactions, leading to a large number of different cyclic structures in one single step. Recently, the use of gold salts and gold complexes has been introduced as an alternative to the traditional methods, providing mild reaction conditions and high group compatibility. This overview focuses on the most recent achievements on gold-catalyzed oxycyclizations, both from alkynols and alkyndiols, and their use in different cascade processes and total synthesis.

引用

页码：4405 / 4416

页数：12

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