Synthesis and dynamic behavior of the heptafluorotrisilacyclohexane anion: A new fluxional silicate with rapid intramolecular exchange of fluoride ligand

被引：47

作者：

Brondani, D ^{[1
]}

Carre, FH ^{[1
]}

Corriu, RJP ^{[1
]}

Moreau, JJE ^{[1
]}

Man, MWC ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,LAB CHIM ORGANOMET,F-34053 MONTPELLIER 01,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1996年 / 35卷 / 03期

关键词：

dynamics; hypervalent compounds; silicon compounds;

D O I：

10.1002/anie.199603241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：324 / 326

页数：3

共 13 条

[1] POLYFUNCTIONAL CARBOSILANES AND ORGANOSILICON COMPOUNDS - SYNTHESIS VIA GRIGNARD REACTIONS [J].

BRONDANI, DJ ;

CORRIU, RJP ;

ELAYOUBI, S ;

MOREAU, JJE ;

MAN, MWC .

TETRAHEDRON LETTERS, 1993, 34 (13) :2111-2114

[2] A NEW TRIALKOXYSILYLATION REACTION, THE CROSS-COUPLING OF (TRI-ISOPROPYLOXYSILYL)METHYL GRIGNARD-REAGENT WITH ORGANIC HALIDES [J].

BRONDANI, DJ ;

CORRIU, RJP ;

ELAYOUBI, S ;

MOREAU, JJE ;

MAN, MWC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :C1-C3

[3]

BRONDANI DJ, UNPUB

[4] REACTIVITY OF PENTACOORDINATE AND HEXACOORDINATE SILICON-COMPOUNDS AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CHUIT, C ;

CORRIU, RJP ;

REYE, C ;

YOUNG, JC .

CHEMICAL REVIEWS, 1993, 93 (04) :1371-1448

[5]

CORRIU RJP, 1985, TOP STEREOCHEM, V15, P43

[6]

CORRIU RJP, 1991, SILICON HETEROATOM B, P1

[7] CHEMISTRY OF ORGANOSILICON COMPOUND .305. HEXAKIS(FLUORODIMETHYLSILYL)BENZENE, HEXAKIS(METHOXYDIMETHYLSILYL)BENZENE, AND RELATED-COMPOUNDS - NOVEL NEUTRAL PENTACOORDINATE STRUCTURES FOR SILICON AND MERRY-GO-ROUND DEGENERATE FLUORINE MIGRATION [J].

EBATA, K ;

INADA, T ;

KABUTO, C ;

SAKURAI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3595-3596

[8]

JOHNSON SE, 1989, INORG CHEM, V28, P3190, DOI 10.1021/ic00315a022

[9]

LAINE RM, 1992, NATO ASI SER SER, V206

[10]

Scherrer G.W, 1990, DRYING SOL GEL SCI

← 1 2 →