Water-assisted highly efficient synthesis of single-walled carbon nanotubes forests from colloidal nanoparticle catalysts

被引:47
作者
Nishino, Hidekazu [1 ]
Yasuda, Satoshi [1 ]
Namai, Tatsunori [1 ]
Futaba, Don N. [1 ]
Yamada, Takeo [1 ]
Yumura, Motoo [1 ]
Iijima, Sumio [1 ]
Hata, Kenji [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Adv Carbon Mat, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1021/jp0723719
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly efficient single-walled carbon nanotube (SWNT) growth from Fe-Mo nanoparticle catalysts made by colloidal synthesis is demonstrated by water-assisted chemical vapor deposition. In a 10 min. growth time, SWNT forests with heights up to 1.5 mm were synthesized possessing a 2.8 nm average diameter, carbon purity above 99.99%, and Brunauer-Emmett-Teller (BET) surface area of 1200 ml/g, which rivals SWNTs grown from sputtered Fe thin films. Realization of high efficiency SWNT growth using catalysts prepared by economical and scalable wet processes opens up a cost-effective route toward the mass'production of SWNT forests.
引用
收藏
页码:17961 / 17965
页数:5
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