Synthesis of o-arylenedizinc compounds from 1-iodo-2-trifluoromethylsulfonyloxybenzenes and zinc powder and their synthetic application

被引：20

作者：

Amano, M ^{[1
]}

Saiga, A ^{[1
]}

Ikegami, R ^{[1
]}

Ogata, T ^{[1
]}

Takagi, K ^{[1
]}

机构：

[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 700, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 47期

关键词：

aryl halides; palladium and compounds; phenols; zinc and compounds;

D O I：

10.1016/S0040-4039(98)01867-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Iodo-2-trifluoromethylsulfonyloxybenzenes readily reacted with Zn powder to yield o-arylenedizine compounds, efficient synthetic equivalents of o-arylene dianions in Pd(0)-catalyzed cross-coupling reactions, wherein the novel insertion of Zn powder into the C-O bond of aryl triflates took place. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8667 / 8668

页数：2

共 9 条

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