o-Bromophenylzinc compound:: A readily available and efficient synthetic equivalent of o-phenylene 1-anion 2-cation

被引：22

作者：

Okano, M ^{[1
]}

Amano, M ^{[1
]}

Takagi, K ^{[1
]}

机构：

[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 700, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(98)00443-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An o-bromophenylzinc compound, first prepared in an excellent yield by the reaction of o-bromoiodobenzene with zinc powder in THF, was found to be an efficient synthetic equivalent of o-phenylene 1-anion 2-cation in Pd(O)-catalyzed stepwise cross-coupling reactions, affording unsymmetrically 12-disubstituted benzenes with diverse substitution patterns and with a variety of functional groups. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3001 / 3004

页数：4

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