The renewable chemicals industry

被引:319
作者
Christensen, Claus Hviid [1 ]
Rass-Hansen, Jeppe [1 ]
Marsden, Charlotte C. [1 ]
Taarning, Esben [1 ]
Egeblad, Kresten [1 ]
机构
[1] Tech Univ Denmark, Dept Chem, Ctr Sustainable & Green Chem, DK-2800 Lyngby, Denmark
关键词
industrial chemistry; renewable resources; sustainable chemistry;
D O I
10.1002/cssc.200700168
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibilities for establishing a renewable chemicals industry featuring renewable resources as the dominant feedstock rather than fossil resources are discussed in this Concept. Such use of biomass can potentially be interesting from both an economical and ecological perspective. Simple and educational tools are introduced to allow initial estimates of which chemical processes could be viable. Specifically, fossil and renewables value chains are used to indicate where renewable feedstocks can be optimally valorized. Additionally, C factors are introduced that specify the amount of CO2 produced per kilogram of desired product to illustrate in which processes the use of renewable resources lead to the most substantial reduction of CO2 emissions. The steps towards a renewable chemicals industry will most likely involve intimate integration of biocatalytic and conventional catalytic processes to arrive at cost-competitive and environmentally friendly processes.
引用
收藏
页码:283 / 289
页数:7
相关论文
共 56 条
[31]  
Milne T., 1998, Biomass Gasifier "Tars": Their Nature, Formation and Conversion, DOI DOI 10.2172/3726
[32]  
Neher A., 1995, US Patent, Patent No. [5,387,720, 5387720, 5 (1995) 387 720]
[33]  
NIELSON JR, 2003, NATO ASI SUSTAINABLE
[34]   From glycerol to value-added products [J].
Pagliaro, Mario ;
Ciriminna, Rosaria ;
Kimura, Hiroshi ;
Rossi, Michele ;
Della Pina, Cristina .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (24) :4434-4440
[35]   BIOMASS AS A SOURCE OF CHEMICAL FEEDSTOCKS - AN ECONOMIC-EVALUATION [J].
PALSSON, BO ;
FATHIAFSHAR, S ;
RUDD, DF ;
LIGHTFOOT, EN .
SCIENCE, 1981, 213 (4507) :513-517
[36]  
Partenheimer W, 2001, ADV SYNTH CATAL, V343, P102, DOI 10.1002/1615-4169(20010129)343:1<102::AID-ADSC102>3.3.CO
[37]  
2-H
[38]   The path forward for biofuels and biomaterials [J].
Ragauskas, AJ ;
Williams, CK ;
Davison, BH ;
Britovsek, G ;
Cairney, J ;
Eckert, CA ;
Frederick, WJ ;
Hallett, JP ;
Leak, DJ ;
Liotta, CL ;
Mielenz, JR ;
Murphy, R ;
Templer, R ;
Tschaplinski, T .
SCIENCE, 2006, 311 (5760) :484-489
[39]   Benzene-free synthesis of hydroquinone [J].
Ran, NQ ;
Knop, DR ;
Draths, KM ;
Frost, JW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (44) :10927-10934
[40]   Bioethanol: fuel or feedstock? [J].
Rass-Hansen, Jeppe ;
Falsig, Hanne ;
Jorgensen, Betina ;
Christensen, Claus H. .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2007, 82 (04) :329-333