Copper-catalyzed oxidation of alcohols to aldehydes and ketones: An efficient, aerobic alternative

被引：636

作者：

Marko, IE

Giles, PR

Tsukazaki, M

Brown, SM

Urch, CJ

机构：

[1] ZENECA PROC TECHNOL DEPT,HUDDERSFIELD WORKS,HUDDERSFIELD HD2 1FF,W YORKSHIRE,ENGLAND

[2] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG42 6ET,BERKS,ENGLAND

来源：

SCIENCE | 1996年 / 274卷 / 5295期

关键词：

D O I：

10.1126/science.274.5295.2044

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

An efficient, copper-based catalyst has been discovered that oxidizes a wide range of alcohols into aldehydes and ketones under mild conditions. This catalytic system utilizes oxygen or air as the ultimate, stoichiometric oxidant, producing water as the only by-product.

引用

收藏

页码：2044 / 2046

页数：3

相关论文

共 25 条

[1]

[Anonymous], COMPREHENSIVE ORGANI

[2] ACTIVATION OF DIOXYGEN AND CATALYTIC-OXIDATION OF ETHANOL TO ACETALDEHYDE AND HYDROGEN-PEROXIDE BY COPPER(I) COMPLEXES CONTAINING 2,2'-BIPYRIDYL AND TERTIARY PHOSPHINE-LIGANDS [J].

BHADURI, S ;

SAPRE, NY .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (12) :2585-2586

[3] REACTION OF OXYGEN WITH COPPER (I)ALKOXIDES [J].

CAPDEVIELLE, P ;

AUDEBERT, P ;

MAUMY, M .

TETRAHEDRON LETTERS, 1984, 25 (39) :4397-4400

[4]

CAPDEVIELLE P, 1993, J CHEM RES S, V10

[5] ON KINETICS AND MECHANISM OF REACTIONS OF HYDROGEN PEROXIDE WITH HYDRAZINE OR HYDROXYLAMINE CATALYZED BY CU2+ AND BY CU2+-2,2'-BIPYRIDYL COMPLEX [J].

ERLENMEYER, H ;

FLIERL, C ;

SIGEL, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (05) :1065-+

[6] COPPER-CATALYZED OXIDATION OF HYDROXY COMPOUNDS BY TERT-BUTYL HYDROPEROXIDE UNDER PHASE-TRANSFER CONDITIONS [J].

FELDBERG, L ;

SASSON, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (15) :1807-1807

[7]

GRIFFITH WP, 1991, DIOXYGEN ACTIVATION

[8] ONE-POT CONVERSION OF PRIMARY ALCOHOLS TO ALPHA-OXYGENATED ALKANALS WITH TEMPO IN COMBINATION WITH MOLECULAR-OXYGEN AND RUTHENIUM COMPLEX [J].

INOKUCHI, T ;

NAKAGAWA, K ;

TORII, S .

TETRAHEDRON LETTERS, 1995, 36 (18) :3223-3226

[9] AEROBIC OXIDATION OF ALCOHOLS TO CARBONYL-COMPOUNDS CATALYZED BY N-HYDROXYPHTHALIMIDE (NHPI) COMBINED WITH CO(ACAC)(3) [J].

IWAHAMA, T ;

SAKAGUCHI, S ;

NISHIYAMA, Y ;

ISHII, Y .

TETRAHEDRON LETTERS, 1995, 36 (38) :6923-6926

[10] ALCOHOL DEHYDROGENATION IN CARBONYL-COMPOUNDS USING THE SYSTEM CUCL-O2-LIGAND [J].

JALLABERT, C ;

RIVIERE, H .

TETRAHEDRON, 1980, 36 (09) :1191-1194