Water-Soluble Phosphonate-Substituted BODIPY Derivatives with Tunable Emission Channels

被引：83

作者：

Bura, Thomas ^{[1
]}

Ziessel, Raymond ^{[1
]}

机构：

[1] CNRS, LCOSA, Ecole Chim Polymeres Mat Strasbourg ECPM, UMR 7515, F-67087 Strasbourg 02, France

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 12期

关键词：

DIPYRROMETHENEBORON DIFLUORIDE BODIPY; DISTYRYL-BORADIAZAINDACENES; SPECTROSCOPIC PROPERTIES; FACILE SYNTHESIS; FLUORESCENCE; DYES; CHEMISTRY; ESTERS; RED;

D O I：

10.1021/ol200969r

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

Water-soluble BODIPY dyes have been readily obtained by introduction of phosphonate fragments either on the boron for the green and yellow emitting dyes or on the side chain for the red emitting dyes. Hydrolysis of the phosphonate is realized at the end of the reaction sequence and allows isolation of the targets by precipitation. All these novel dyes are soluble and fluorescent in water with quantum yields in the 23-59% range and emission wavelength spanning from 667 to 509 nm.

引用

页码：3072 / 3075

页数：4

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