Interplay of factors affecting Raman scattering in cadmium chalcogenide nanocrystals in dielectric media

被引:29
作者
Azhniuk, Yu M. [1 ]
Hutych, Yu I. [1 ]
Lopushansky, V. V. [1 ]
Raevskaya, A. E. [2 ]
Stroyuk, A. L. [2 ]
Kuchmiy, S. Ya [2 ]
Gomonnai, A. V. [1 ]
Zahn, D. R. T. [3 ]
机构
[1] Natl Acad Sci Ukraine, Inst Electron Phys, Univ Ska Str 21, UA-88017 Uzhgorod, Ukraine
[2] Ukr Nat Acad Sci, Inst Phys Chem, UK-03028 Kiev, Ukraine
[3] Tech Univ Chemnitz, Semicond Phys, D-09107 Chemnitz, Germany
来源
XIII INTERNATIONAL SEMINAR ON PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 79卷
关键词
D O I
10.1088/1742-6596/79/1/012017
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Micro-Raman spectra of CdS and CdSe nanocrystals embedded in different dielectric media (borosilicate glass, gelatin, polyacrylamide, polyvinyl alcohol) are studied. The observed Raman features are discussed with the account of confinement-related selection rules relaxation, scattering by surface phonons, and host matrix pressure. For nanocrystals grown in borosilicate glass a pronounced resonant dependence of surface phonon frequency on the excitation wavelength is observed. The effect of the excitation wavelength is much stronger than that of the nanocrystal size or the dielectric matrix type.
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页数:6
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共 35 条
[1]   Resonant Raman studies of compositional and size dispersion of CdS1-xSex nanocrystals in a glass matrix [J].
Azhniuk, YM ;
Milekhin, AG ;
Gomonnai, AV ;
Lopushansky, VV ;
Yukhymchuk, VO ;
Schulze, S ;
Zenkevich, EI ;
Zahn, DRT .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (49) :9069-9082
[2]   CONFINEMENT EFFECTS ON THE LO-PHONONS IN CDSEXSE1-X DOPED GLASSES [J].
BERSANI, D ;
LOTTICI, PP .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1992, 174 (02) :575-582
[3]   QUANTUM CONFINEMENT EFFECTS OF SEMICONDUCTING MICROCRYSTALLITES IN GLASS [J].
BORRELLI, NF ;
HALL, DW ;
HOLLAND, HJ ;
SMITH, DW .
JOURNAL OF APPLIED PHYSICS, 1987, 61 (12) :5399-5409
[4]   Resonant Raman effect enhanced by surface plasmon excitation of CdSe nanocrystals embedded in thin SiO2 films [J].
Brioude, A ;
Bellessa, J ;
Rabaste, S ;
Champagnon, B ;
Sphanel, L ;
Mugnier, J ;
Plenet, JC .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2744-2748
[5]   THE EFFECTS OF MICROCRYSTAL SIZE AND SHAPE ON THE ONE PHONON RAMAN-SPECTRA OF CRYSTALLINE SEMICONDUCTORS [J].
CAMPBELL, IH ;
FAUCHET, PM .
SOLID STATE COMMUNICATIONS, 1986, 58 (10) :739-741
[6]   Growth and optical properties of semiconductor nanocrystals in a glass matrix [J].
Ekimov, A .
JOURNAL OF LUMINESCENCE, 1996, 70 :1-20
[7]   Confinement-, surface- and disorder-related effects in the resonant Raman spectra of nanometric CdS1-xSex crystals [J].
Gomonnai, AV ;
Azhniuk, YM ;
Yukhymchuk, VO ;
Kranjcec, M ;
Lopushansky, VV .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2003, 239 (02) :490-499
[8]   Size-dependent surface phonon mode of CdSe quantum dots [J].
Hwang, YN ;
Park, SH ;
Kim, D .
PHYSICAL REVIEW B, 1999, 59 (11) :7285-7288
[9]   Effect of lattice contraction on the Raman shifts of CdSe quantum dots in glass matrices [J].
Hwang, YN ;
Shin, SH ;
Park, HL ;
Park, SH ;
Kim, U ;
Jeong, HS ;
Shin, EJ ;
Kim, D .
PHYSICAL REVIEW B, 1996, 54 (21) :15120-15124
[10]   Raman spectra of semiconductor nanoparticles: Disorder-activated phonons [J].
Ingale, A ;
Rustagi, KC .
PHYSICAL REVIEW B, 1998, 58 (11) :7197-7204