Single-molecule studies of electronic energy transfer in a diblock conjugated polymer

被引:16
作者
Grey, JK
Kim, DY
Lee, YJ
Gutierrez, JJ
Luong, N
Ferraris, JP
Barbara, PF [1 ]
机构
[1] Univ Texas, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA
[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
[3] Univ Texas, Dept Chem, Austin, TX 75083 USA
关键词
energy transfer; fluorescence; interfaces; polymers; single-molecule studies;
D O I
10.1002/anie.200501388
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Graph Presented) Energy transfer at the interface of two dissimilar conjugated polymer chains (see picture; DMOS = 2-dimethyloctylsilyl-p- phenylenevinylene; MEH = 2-methoxy-5-(2′-ethylhexyloxy)-p- phenylenevinylene) has been studied using single-molecule spectroscopy. Morphological features control energy-transfer processes between the blocks and lead to strongly heterogeneous efficiencies of energy transfer. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6207 / 6210
页数:4
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