Mesoporous Silica with Site-Isolated Amine and Phosphotungstic Acid Groups: A Solid Catalyst with Tunable Antagonistic Functions for One-Pot Tandem Reactions

被引：180

作者：

Shiju, N. Raveendran ^{[1
]}

Alberts, Albert H. ^{[1
]}

Khalid, Syed ^{[3
]}

Brown, David R. ^{[2
]}

Rothenberg, Gadi ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[2] Univ Huddersfield, Dept Chem & Biol Sci, Mat & Catalysis Res Ctr, Queensgate HD1 3DH, W Yorkshire, England

[3] Brookhaven Natl Lab, Natl Synchrotron Light Source, Upton, NY 11973 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 41期

基金：

英国工程与自然科学研究理事会;

关键词：

heterogeneous catalysis; mesoporous materials; NMR spectroscopy; HETEROGENEOUS CATALYSIS; COOPERATIVE CATALYSIS; BASE; NANOCATALYSTS; NANOPARTICLES; COPOLYMER; TRIBLOCK; DESIGN; PORES; THIOL;

D O I：

10.1002/anie.201101449

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coniuga et impera: A bifunctional solid catalyst is prepared by combining acid and base functions on mesoporous silica supports (see picture). The co-existence of these functions is shown by a two-step reaction sequence in one pot. Excellent product yields, which cannot be obtained by separated acid and base functions in one pot, show the validity of our concept. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9615 / 9619

页数：5

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