Internal/external use of dendrimer in catalysis

被引:16
作者
Chung, YM [1 ]
Rhee, HK
机构
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
[2] Seoul Natl Univ, Inst Chem Proc, Seoul 151742, South Korea
关键词
dendrimer; immobilization; asymmetric synthesis; chiral auxiliary; encapsulation; nanoreactor; nanoparticle; bimetal; organic-inorganic hybrid; catalysis;
D O I
10.1007/BF02705384
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dendrimers, well-defined hyper-branched macromolecules with characteristic globular structures, have inspired chemists and chemical engineers to develop new materials and several applications have been explored. The dendritic molecule has emerged as an attractive material in the field of catalysis and various dendrimer catalysts have been applied not only to catalytic reactions but also to non-catalytic ones such as nanoscale reactor systems. This article presents a review of research work on the dendrimer-based catalysis involving the rational design of homogeneous or heterogeneous chiral dendrimer catalysts for enantioselective reactions and the synthesis of catalytically active bimetallic nanoparticles in the presence of dendrimer as a template.
引用
收藏
页码:81 / 97
页数:17
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