Chemistry of polycarbon species: from clusters to molecular devices

被引：104

作者：

Akita, Munetaka ^{[1
]}

Koike, Takashi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

DALTON TRANSACTIONS | 2008年 / 27期

关键词：

D O I：

10.1039/b802069h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polycarbon species with pi-conjugated systems interact with attached metal fragments to exhibit a variety of intriguing structural features and chemical properties. In this Perspective, following an introductory account of polycarbon cluster compounds and the unique chemical transformations on them which cannot easily be realized by mononuclear species, the properties of polynuclear complexes connected by pi-conjugated carbon-rich bridging ligands will be discussed with emphasis on those applicable to molecular electronics, e. g. wire-like behavior (molecular wires), higher dimensional systems (branch circuits), and switching functions.

引用

页码：3523 / 3530

页数：8

共 133 条

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