Silicone grease: A serendipitous reagent for the synthesis of exotic molecular and supramolecular compounds

被引：51

作者：

Haiduc, I ^{[1
]}

机构：

[1] Univ Babes Bolyai, Fac Chim, R-3400 Cluj Napoca, Romania

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 01期

关键词：

D O I：

10.1021/om034176w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A review describing a series of (mostly accidental) intriguing reactions of silicone grease with various highly polar organometallic reagents is presented. The products are unusual and unexpected (sometimes supramolecular) compounds, incorporating various fragments of the parent polysiloxane chain, such as disiloxane or other oligosiloxane units, (OSiMe2)(n)O (n = 2, 3, etc.), dimethylsilanone Me2SiO, dimethylsilylene Me2Si, and other methylsilicon moieties.

引用

页码：3 / 8

页数：6

共 45 条

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