A unique self-assembled tricyclic stannasiloxane containing a planar Sn3SiO5 fused 6.4.4 tricyclic ring system

被引:25
作者
Cervantes-Lee, F [1 ]
Sharma, HK [1 ]
Haiduc, I [1 ]
Pannell, KH [1 ]
机构
[1] Univ Texas, Dept Chem, El Paso, TX 79968 USA
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 01期
关键词
D O I
10.1039/a707121c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The compound (Bu4Sn2)-Sn-t(Me2Si)O-3 . (Bu2Sn)-Sn-t(OH)(2) displays a unique tricyclic structure consisting of fused six-membered Sn2SiO3 and four-membered Sn2O2 rings to form a planar SiSn3O4 skeleton, with severely distorted trigonal bipyramidal co-ordination at tin and tetrahedral co-ordination at silicon.
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页码:1 / 2
页数:2
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