Asymmetric conjugate addition of metal alkyl reagents catalyzed by copper complexes with BINPO: a hemilabile P,O-heterobidentate axially chiral ligand

被引：49

作者：

Fuchs, N

d'Augustin, M

Humam, M

Alexakis, A

Taras, R

Gladiali, S

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] Univ Geneva, Dept Chim Organ, CH-1211 Geneva, Switzerland

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 19期

关键词：

D O I：

10.1016/j.tetasy.2005.08.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We herein report the use of a new class of P,O-bidentate arylphosphine ligand for the asymmetric copper catalyzed conjugate addition of dialkylzinc and trialkylaluminium with the enantiomeric excesses reaching 91% while (R)-muscone was obtained with 77% ee. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3143 / 3146

页数：4