Indium-mediated organometallic reactions in aqueous media. Stereoselectivity in the crotylation of sulfonimines bearing a proximal chelating group

被引:80
作者
Lu, WS [1 ]
Chan, TH [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
关键词
D O I
10.1021/jo0018038
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of sulfonimines having proximal chelating groups with crotyl bromide and indium in aqueous media gave alpha -crotylation products stereoselectively with syn-selectivity.
引用
收藏
页码:3467 / 3473
页数:7
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