Two new furostanol glycosides from the fibrous root of Ophiopogon japonicus (Thunb.) Ker-Gawl

被引：9

作者：

Duan, Chang-Ling ^{[1
]}

Ma, Xiao-Feng ^{[3
]}

Jiang, Yong ^{[2
]}

Liu, Jian-Xun ^{[1
]}

Tu, Peng-Fei ^{[2
]}

机构：

[1] China Acad Chinese Med Sci, Xiyuan Hosp, Beijing 100091, Peoples R China

[2] Peking Univ, Sch Pharmaceut Sci, Beijing 100191, Peoples R China

[3] Chinese Acad Sci, Grad Univ, Coll Life Sci, Beijing 100049, Peoples R China

来源：

JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH | 2010年 / 12卷 / 09期

关键词：

Ophiopogon japonicus; furostanol glycoside; Liliaceae; STEROIDAL SAPONINS;

D O I：

10.1080/10286020.2010.495332

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Two new furostanol glycosides, ophiopogonins H (1) and I (2), were isolated from the fibrous root of Ophiopogon japonicus. The structures of 1 and 2 were established as (25R)-26-[(O--d-glucopyranosyl-(12)--d-glucopyranosyl)]-22-hydroxyfurost-5-ene-3-O-[-l-rhamnopyranosyl-(12)]--d-glucopyranoside and (25R)-26-[(O--d-glucopyranosyl-(12)--d-glucopyranosyl)]-20-hydroxyfurost-5,22-diene-3-O-[-l-rhamnopyranosyl-(12)]--d-glucopyranoside on the basis of spectroscopic means including HR-ESI-MS, 1D and 2D NMR experiments.

引用

页码：745 / 751

页数：7

共 13 条

[1] NMR spectroscopy of steroidal sapogenins and steroidal saponins: An update [J].

Agrawal, PK ;

Jain, DC ;

Pathak, AK .

MAGNETIC RESONANCE IN CHEMISTRY, 1995, 33 (12) :923-953

[2] Homoisoflavonoids from Ophiopogon japonicus Ker-Gawler [J].

Anh, NTH ;

Van Sung, T ;

Porzel, A ;

Franke, K ;

Wessjohann, LA .

PHYTOCHEMISTRY, 2003, 62 (07) :1153-1158

[3]

Argrawal P. K., 2005, STEROIDS, V70, P715

[4] Furostanol saponins in Allium caepa L. var. tropeana seeds [J].

Dini, I ;

Tenore, GC ;

Trimarco, E ;

Dini, A .

FOOD CHEMISTRY, 2005, 93 (02) :205-214

[5]

Do A. C., 1995, J NAT PRODUCTS, V58, P778

[6] Spirostanol Saponins from the Fibrous Roots of Ophiopogon japonicus (THUNB.) KER-GAWL [J].

Duan, Chang-Ling ;

Li, Yu-Juan ;

Li, Peng ;

Jiang, Yong ;

Liu, Jian-Xun ;

Tu, Peng-Fei .

HELVETICA CHIMICA ACTA, 2010, 93 (02) :227-232

[7]

Jiangsu New Medicinal College, 1986, ZHONG YAO DA CI DIAN, V3, P2082

[8] New furostanol saponins from Allium ascalonicum L. [J].

Kang, Li-Ping ;

Liu, Zhi-Jun ;

Zhang, Lei ;

Tan, Da-Wei ;

Zhao, Yang ;

Zhao, Yu ;

Chen, He-Bing ;

Ma, Bai-Ping .

MAGNETIC RESONANCE IN CHEMISTRY, 2007, 45 (09) :725-733

[9] Steroidal saponins from Smilax china and their anti-inflammatory activities [J].

Shao, Bo ;

Guo, Hongzhu ;

Cui, Yajun ;

Ye, Min ;

Han, Jian ;

Guo, Dean .

PHYTOCHEMISTRY, 2007, 68 (05) :623-630

[10]

WATANABE Y, 1990, Shoyakugaku Zasshi, V44, P117

← 1 2 →