One-pot synthesis of aromatic poly(1,3,4-oxadiazole)s in novel solvents - ionic liquids

被引：42

作者：

Lozinskaya, EI ^{[1
]}

Shaplov, AS ^{[1
]}

Kotseruba, MV ^{[1
]}

Komarova, LI ^{[1
]}

Lyssenko, KA ^{[1
]}

Antipin, MY ^{[1
]}

Golovanov, DG ^{[1
]}

Vygodskii, YS ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow, Russia

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2006年 / 44卷 / 01期

关键词：

condensing agent; direct polycondensation; ionic liquids; poly(1,3,4-oxadiazole)s; polyhydrazides; triphenyl phosphite;

D O I：

10.1002/pola.21141

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The new convenient method for the synthesis of high molecular weight aromatic poly(1,3,4-oxadiazole)s (PODS) has been proposed. These polymers were prepared by "one-pot" procedure from dicarboxylic acid and hydrazine's salt (sulfate, phosphate) or dicarboxylic acid dihydrazides. The mixture of ionic liquid and triphenyl phosphite was used both as a solvent and condensing agent. The polycyclization occurred at a sufficiently low temperature of 210 degrees C for 2-5 h and resulted in obtaining film-forming PODS having inherent viscosities up to 0.9 dL/g and good thermal stability. 0 2005 Wiley Periodicals, Inc.

引用

页码：380 / 394

页数：15

共 63 条

[1]

ABDULSADA AAK, 1995, Patent No. 21871

[2] Radical polymerization in a chiral ionic liquid: Atom transfer radical polymerization of acrylates [J].

Biedron, T ;

Kubisa, P .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (15) :3454-3459

[3] Cationic polymerization of styrene in a neutral ionic liquid [J].

Biedron, T ;

Kubisa, P .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (13) :3230-3235

[4]

Biedron T, 2001, MACROMOL RAPID COMM, V22, P1237, DOI 10.1002/1521-3927(20011001)22:15<1237::AID-MARC1237>3.0.CO

[5]

2-E

[6] One-pot synthesis of copoly(aliphatic-aromatic) oxadiazoles: how to control the formation of random or block structures? [J].

Briffaud, T ;

Garapon, J ;

Sillion, B .

HIGH PERFORMANCE POLYMERS, 2001, 13 (02) :S197-S215

[7] Copper(I) mediated living radical polymerisation in an ionic liquid [J].

Carmichael, AJ ;

Haddleton, DM ;

Bon, SAF ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238

[8] CATALYTIC DIMERIZATION OF ALKENES BY NICKEL-COMPLEXES IN ORGANOCHLOROALUMINATE MOLTEN-SALTS [J].

CHAUVIN, Y ;

GILBERT, B ;

GUIBARD, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1715-1716

[9]

DAVIDIS E, 1896, J PRAKT CHEM, V54, P74

[10] Atom transfer radical polymerization of ionic liquid 2-(1-butylimidazolium-3-yl)ethyl methacrylate tetrafluoroborate [J].

Ding, SJ ;

Tang, HD ;

Radosz, M ;

Shen, YQ .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (22) :5794-5801

← 1 2 3 4 5 6 7 →