Rich chemistry of nitroso compounds

被引：257

作者：

Yamamoto, H ^{[1
]}

Momiyama, N ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 28期

关键词：

D O I：

10.1039/b503212c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrosobenzene or nitrosopyridine are found to be attractive electrophiles in catalytic enantioselective carbon-nitrogen and/or carbon-oxygen bond forming reactions. In the presence of designer Lewis or Bronsted acid catalysts, catalytic enantioselective O- and N-nitroso aldol reaction or nitroso Diels-Alder reaction proceed smoothly. The scope and limitation of new catalytic processes are described.

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页码：3514 / 3525

页数：12

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