BING-2:: a layered tin-oxalate potassium fluoride, KSn(C2O4)F

被引：11

作者：

Salami, TO

Zavalij, PY

Oliver, SRJ ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801008959

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, KSn(C2O4)F, is a two-dimensional material related to our previously reported three-dimensional framework, Na4Sn4(C2O4)(3)F-6. Both are alkali-metal tin-oxalate materials, but here the compound is layered and has potassium in place of sodium. The material was synthesized solvothermally at 423 K and crystallized in the monoclinic space group P2(1)/c. The structure consists of potassium fluoride layers in the bc plane, which are sandwiched on both sides by tin-oxalate chains that extend along the c axis.

引用

页码：I49 / i51

页数：3

共 10 条

[1] Tin(II) oxalates synthesized in the presence of structure-directing organic amines: Members of a potentially vast class of new open-framework and related materials [J].