Triblock copolymer synthesis of highly ordered large-pore periodic mesoporous organosilicas with the aid of inorganic salts

被引:209
作者
Guo, WP [1 ]
Park, JY [1 ]
Oh, MO [1 ]
Jeong, HW [1 ]
Cho, WJ [1 ]
Kim, I [1 ]
Ha, CS [1 ]
机构
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Pusan 609735, South Korea
关键词
D O I
10.1021/cm0258023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This communication describes the first preparation of highly ordered large-pore hexagonal periodic mesoporous organosilicas (PMOs) using triblock copolymer P123 as the template and inorganic salts as the auxiliary agents under strongly acidic conditions. The long-range structural order of the PMOs results from the enhanced self-assembly interaction imparted by inorganic salts.
引用
收藏
页码:2295 / +
页数:5
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