Facile synthesis of bidimensional ferrocenyl-based branched oligomers by palladium-catalyzed coupling reactions

被引：23

作者：

Peruga, A

Mata, JA

Sainz, D

Peris, E ^{[1
]}

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12080 Castellon de La Plana, Spain

[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

关键词：

ferrocenes; metal-containing dendrimers; star-shaped complexes; electrochemistry;

D O I：

10.1016/S0022-328X(01)00903-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New ferrocenyl-based star-shaped complexes have been obtained by palladium-catalyzed reactions. The synthetic method reported shows an advantage over the traditional Wittig reaction for the synthesis of olefinated compounds, both in yields and in selectivity towards the all-E isomers. The electrochemistry of the compounds has been studied. The crystal structure of E-ferrocenyl-4-(vinylphenyl)vinylene, one of the starting complexes to the star-shaped compounds, has been determined by means of single crystal X-ray diffraction. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：191 / 197

页数：7

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