The confined cavity of a coordination cage suppresses the photocleavage of α-diketones to give cyclization products through kinetically unfavorable pathways

被引：77

作者：

Furusawa, Takahito ^{[1
]}

Kawano, Masaki ^{[1
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 30期

关键词：

alpha-diketones; cage compounds; cyclization; photochemistry; self-assembly;

D O I：

10.1002/anie.200701250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) It's a trap: The photochemical homolytic cleavage of an α-diketone leading to degradation products was suppressed through the encapsulation of the diketone in a self-assembled cage. Instead, intramolecular cyclization products were formed through otherwise unfavorable (kinetically hidden) reaction pathways. This provides an approach to find new reactions of photolabile compounds that had been abandoned because of predominant cleavage reactions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5717 / 5719

页数：3

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