Efficient white-light-emitting diodes based on polyfluorene doped with fluorescent chromophores

被引:23
作者
Fan, Suqin [1 ]
Sun, Mingliang [1 ]
Wang, Jian [1 ]
Yang, Wei [1 ]
Cao, Yong [1 ]
机构
[1] S China Univ Technol, Inst Polymer Opt Elect Mat & Devices, Key Lab Specially Funct Mat, Minist Educ, Guangzhou 510640, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1063/1.2812569
中图分类号
O59 [应用物理学];
学科分类号
摘要
Orange-red emitting small molecule chromorephores, 4,7-di-2-thienyl-2,1,3-benzothiadiazole, 4,7-(2'-diselenophenyl)-2,1,3-benzothiadiazole, and 4,7-bis(N-methylpyrrol-2-yl)-2,1,3-benzo-thiadiazole were synthesized and used for fabrication of fluorescent white-emitting device with polyfluorene (PFO) as host by solution processing. By careful controlling of dopant concentration, balanced narrow band-gap (NGB) electroluminescence (EL) emission can be obtained by solution processing due to the incomplete energy transfer from PFO to narrow band gap molecules. EL spectra of the obtained devices were very stable at a wide range of operating voltage. The best white-emitting device reached luminous efficiency of 7.54 cd/A with the CIE coordinates (0.33, 0.34) at luminance over 1000 cd/m(2). (C) 2007 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 19 条
[1]   White organic light-emitting diodes based on improved polyfluorene derivative [J].
Cong, Yang ;
Chen, Zhijian ;
Li, Fushan ;
Gong, Qihuang .
OPTICAL MATERIALS, 2006, 28 (8-9) :1084-1087
[2]   Comparative study on polymer light-emitting devices based on blends of polyfluorene and 4,7-di-2-thienyl-2,1,3-benzothiadiazole with devices based on copolymer of the same composition [J].
Fan, Suqin ;
Sun, Mingliang ;
Chen, Zhao ;
Luo, Jie ;
Hou, Qiong ;
Peng, Junbiao ;
Yang, Hong ;
Zhang, Dengqing ;
Li, Fuyou ;
Cao, Yong .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (22) :6113-6117
[3]   White electrophosphorescence from semiconducting polymer blends [J].
Gong, X ;
Ma, WL ;
Ostrowski, JC ;
Bazan, GC ;
Moses, D ;
Heeger, AJ .
ADVANCED MATERIALS, 2004, 16 (07) :615-+
[4]   Multilayer polymer light-emitting diodes: White-light emission with high efficiency [J].
Gong, X ;
Wang, S ;
Moses, D ;
Bazan, GC ;
Heeger, AJ .
ADVANCED MATERIALS, 2005, 17 (17) :2053-+
[5]   Novel red-emitting fluorene-based copolymers [J].
Hou, Q ;
Xu, YS ;
Yang, W ;
Yuan, M ;
Peng, JB ;
Cao, Y .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) :2887-2892
[6]   Improving the power efficiency of white light-emitting diode by doping electron transport material [J].
Huang, Jinsong ;
Hou, Wei-Jen ;
Li, Juo-Hao ;
Li, Gang ;
Yang, Yang .
APPLIED PHYSICS LETTERS, 2006, 89 (13)
[7]   Achieving high-efficiency polymer white-light-emitting devices [J].
Huang, JS ;
Li, G ;
Wu, E ;
Xu, QF ;
Yang, Y .
ADVANCED MATERIALS, 2006, 18 (01) :114-117
[8]   High-efficiency white-light-emitting devices from a single polymer by mixing singlet and triplet emission [J].
Jiang, Jiaxing ;
Xu, Yunhua ;
Yang, Wei ;
Guan, Rong ;
Liu, Zhenqin ;
Zhen, Hongyu ;
Cao, Yong .
ADVANCED MATERIALS, 2006, 18 (13) :1769-+
[9]   Efficient pure-white organic light-emitting diodes with a solution-processed, binary-host employing single emission layer [J].
Jou, JH ;
Sun, MC ;
Chou, HH ;
Li, CH .
APPLIED PHYSICS LETTERS, 2006, 88 (14)
[10]   Energy transfer in polymer electrophosphorescent light emitting devices with single and multiple doped luminescent layers [J].
Kawamura, Y ;
Yanagida, S ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (01) :87-93