Highly efficient Near-IR emitting YbNb and Yb/Al helicates

被引：99

作者：

Albrecht, Markus

Osetska, Olga

Froehlich, Roland

Buenzli, Jean-Claude G.

Aebischer, Annina

Gumy, Frederic

Hamacek, Josef

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[3] Ecole Polytech Fed Lausanne, Lab Lanthanide Supramol Chem, CH-1015 Lausanne, Switzerland

[4] Univ Geneva, Dept Inorgan Analyt & Appl Chem CHIAM, CH-1211 Geneva 4, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 46期

关键词：

D O I：

10.1021/ja0768688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homo- and heterodinuclear Yb/Yb and Gd/Gd or Yb/Al and Gd/Al helicates are obtained from 8-hydroxyquinoline-derived ligands and metal ions in a potassium-templated self-assembly process. X-ray structural investigations reveal an unusual pi-type coordination of the template to a vinylic unit. The compounds show high stability in solution and efficient NIR emission.

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页码：14178 / +

页数：3

相关论文

共 34 条

[21] Correlation between the lowest triplet state energy level of the ligand and lanthanide(III) luminescence quantum yield [J].

Latva, M ;

Takalo, H ;

Mukkala, VM ;

Matachescu, C ;

RodriguezUbis, JC ;

Kankare, J .

JOURNAL OF LUMINESCENCE, 1997, 75 (02) :149-169

[22] Supramolecular coordination chemistry in aqueous solution: Lanthanide ion-induced triple helix formation [J].

Lessmann, JJ ;

Horrocks, WD .

INORGANIC CHEMISTRY, 2000, 39 (15) :3114-3124

[23] The measurement of circular polarization in the near-IR luminescence from chiral complexes of Yb(III) and Nd(III) [J].

Maupin, CL ;

Dickins, RS ;

Govenlock, LG ;

Mathieu, CE ;

Parker, D ;

Williams, JAG ;

Riehl, JP .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (29) :6709-6717

[24] Mono- and polymetallic lanthanide-containing functional assemblies:: a field between tradition and novelty [J].

Piguet, C ;

Bünzli, JCG .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (06) :347-358

[25] Isolated d-f pairs in supramolecular complexes with tunable structural and electronic properties [J].

Piguet, C ;

Edder, C ;

Rigault, S ;

Bernardinelli, G ;

Bünzli, JCG ;

Hopfgartner, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (22) :3999-4006

[26] RELATIONS BETWEEN INTRAMOLECULAR ENERGY TRANSFER EFFICIENCIES AND TRPLET STATE ENERGIES IN RARE EARTH BETA-DIKETONE CHELATES [J].

SATO, S ;

WADA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (07) :1955-+

[27] Organic infrared optical materials and devices based on an organic rare earth complex [J].

Suzuki, H ;

Hattori, Y ;

Iizuka, T ;

Yuzawa, K ;

Matsumoto, N .

THIN SOLID FILMS, 2003, 438 :288-293

[28] ORGANIC ELECTROLUMINESCENT DIODES [J].

TANG, CW ;

VANSLYKE, SA .

APPLIED PHYSICS LETTERS, 1987, 51 (12) :913-915

[29] Tuning the decay time of lanthanide-based near infrared luminescence from micro- to milliseconds through d→f energy transfer in discrete heterobimetallic complexes [J].

Torelli, S ;

Imbert, D ;

Cantuel, M ;

Bernardinelli, G ;

Delahaye, S ;

Hauser, A ;

Bünzli, JCG ;

Piguet, C .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (11) :3228-3242

[30] Rare-earth quinolinates: Infrared-emitting molecular materials with a rich structural chemistry [J].

Van Deun, R ;

Fias, P ;

Nockemann, P ;

Schepers, A ;

Parac-Vogt, TN ;

Van Hecke, K ;

Van Meervelt, L ;

Binnemans, K .

INORGANIC CHEMISTRY, 2004, 43 (26) :8461-8469

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