Iron(II) complexes utilising terpyridine containing [2]rotaxanes as ligands

被引：38

作者：

Davidson, GJE ^{[1
]}

Loeb, SJ ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

DALTON TRANSACTIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b308553h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A terpyridine chelating group is incorporated into a cationic ( dipyridinium) ethane axle and self-assembly synthesis used to create three [2] rotaxanes utilising 24-membered crown ether wheels: 24-crown-8, dibenzo-24-crown-8 and dinaphtho-24-crown-8 ether. The resulting [2] rotaxanes are characterised by H-1 NMR spectroscopy, X-ray crystallography and mass spectrometry. The ability of these rotaxanes to act as ligands is demonstrated by the formation of bis(terpy) chelate complexes of Fe(II). The effect of using a rotaxane as a ligand is probed by UV-vis absorption spectroscopy of the Fe(II) complexes.

引用

页码：4319 / 4323

页数：5

共 42 条

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