Nucleation-elongation: a mechanism for cooperative supramolecular polymerization

被引：396

作者：

Zhao, DH

Moore, JS

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[2] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 20期

关键词：

D O I：

10.1039/b308788c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetic and thermodynamic characteristics of polymerizations following a cooperative, nucleation-elongation mechanism are discussed in comparison to those of non-cooperative, isodesmic polymerizations. Nucleation-elongation polymerization is a relatively unexplored avenue of synthetic polymer chemistry and offers some unique and interesting thermodynamic and kinetic attributes not found in the more classical mechanisms of polymer chemistry.

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页码：3471 / 3491

页数：21

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